Theory of Colours — trans. Charles Lock Eastlake (1840)

The glasses employed for the experiments are to be regarded as the utmost possible practical approach to transparence. By the intimate contact, however, occasioned by the pressure applied to them, their surfaces, we are persuaded, immediately become in a very slight degree dimmed. Within this semi-transparence the colours immediately appear, and every circle comprehends the whole scale; for when the two opposites, yellow and blue, are united by their red extremities, pure red appears: the green, on the other hand, as in prismatic experiments, when yellow and blue touch.

453.

We have already repeatedly found that where colour exists at all, the whole scale is soon called into existence; a similar principle may be said to lurk in the nature of every physical phenomenon; it already follows, from the idea of polar opposition, from which an elementary unity or completeness results.

454.

The fact that a colour exhibited by transmitted light is different from that displayed by reflected light, reminds us of those dioptrical colours of the first class which we found were produced precisely in the same way through semi-opacity. That here, too, a diminution of transparency exists there can scarcely be a doubt; for the adhesion of the perfectly smooth plates of glass (an adhesion so strong that they remain hanging to each other) produces a degree of union which deprives each of the two surfaces, in some degree, of its smoothness and transparence. The fullest proof may, however, be found in the fact that in the centre, where the lens is most strongly pressed on the other glass, and where a perfect union is accomplished, a complete transparence takes place, in which we no longer perceive any colour. All this may be hereafter confirmed in a recapitulation of the whole.

455.

Second condition.--If after breathing on a plate of glass, the breath is merely wiped away with the finger, and if we then again immediately breathe on the glass, we see very vivid colours gliding through each other; these, as the moisture evaporates, change their place, and at last vanish altogether. If this operation is repeated, the colours are more vivid and beautiful, and remain longer than they did the first time.

456.

Quickly as this appearance passes, and confused as it appears to be, I have yet remarked the following effects:--At first all the principal colours appear with their combinations; on breathing more strongly, the appearance may be perceived in some order. In this succession it may be remarked, that when the breath in evaporating becomes contracted from all sides towards the centre, the blue colour vanishes last.

457.

The phenomenon appears most readily between the minute lines, which the action of passing the fingers leaves on the clear surface; a somewhat rough state of the surface of the glass is otherwise requisite. On some glass the appearance may be produced by merely breathing; in other cases the wiping with the fingers is necessary: I have even met with polished mirror-glasses, one side of which immediately showed the colours vividly; the other not. To judge from some remaining pieces, the former was originally the front of the glass, the latter the side which was covered with quicksilver.

458.

These experiments may be best made in cold weather, because the glass may be more quickly and distinctly breathed upon, and the breath evaporates more suddenly. In severe frost the phenomenon may be observed on a large scale while travelling in a carriage; the glasses being well cleaned, and all closed. The breath of the persons within is very gently diffused over the glass, and immediately produces the most vivid play of colours. How far they may present a regular succession I have not been able to remark; but they appear particularly vivid when they have a dark object as a background. This alternation of colours does not, however, last long; for as soon as the breath gathers in drops, or freezes to points of ice, the appearance is at once at an end.

459.

Third condition.--The two foregoing experiments of the pressure and breathing may be united; namely, by breathing on a plate of glass, and immediately after pressing the other upon it. The colours then appear as in the case of two glasses unbreathed upon, with this difference, that the moisture occasions here and there an interruption of the undulations. On pushing one glass away from the other the moisture appears iridescent as it evaporates.

460.

It might, however, be asserted that this combined experiment exhibits no more than each single experiment; for it appears the colours excited by pressure disappear in proportion as the glasses are less in contact, and the moisture then evaporates with its own colours.

461.

Fourth condition.--Iridescent appearances are observable in almost all bubbles; soap-bubbles are the most commonly known, and the effect in question is thus exhibited in the easiest mode; but it may be observed in wine, beer, in pure spirit, and again, especially, in the froth of chocolate.

462.